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BaTiO3基Au纳米颗粒复合薄膜的制备及其光学性质研究

Preparation and Optical Properties of Au/BaTiO3 Nanoparticle Composite Thin Films

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【作者】 戴树刚杨勇黄为民施剑林

【Author】 DAI Shu-Gang, YANG Yong, HUANG Wei-Min, SHI Jian-Lin(State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences Shanghai 200050, China)

【机构】 中国科学院上海硅酸盐研究所高性能陶瓷与超微结构国家重点实验室中国科学院上海硅酸盐研究所高性能陶瓷与超微结构国家重点实验室 上海 200050上海 200050上海 200050

【摘要】 采用溶胶-凝胶(sol-gel)方法,成功的将高体积百分比的Au纳米颗粒复合到BaTiO3的非晶薄膜中,并对其光学性质进行了研究.用XRD、TEM、椭偏仪、吸收光谱、光克尔效应0KE(Optical Kerr Effect)方法对薄膜进行了表征和测试.从吸收光谱观察到表面等离子体共振SPR(Surface Plasma Resonance)峰随热处理温度升高而红移的现象.光学非线性测试表明薄膜具有高的三阶非线性极化率x(3)和超快的响应时间.

【Abstract】 High doping level of Au nanoparticles was successfully incorporated into sol-gel derived amorphous BaTiO3 thin films, and the optical properties of samples were studied. The characteristics of samples were investigated by using XRD, TEM, absorption spectra, and OKE(Optical Kerr Effect) techniques. Red shift of SPR (surface plasma resonance) absorption along with the increase of treat temperature was observed by absorption spectra. Films exhibited a larger third nonlinear susceptibility x(3) and superfast response time in the nonlinear optical test.

【基金】 国家自然科学基金(50172057)
  • 【文献出处】 无机材料学报 ,Journal of Inorganic Materials , 编辑部邮箱 ,2003年02期
  • 【分类号】TB383
  • 【被引频次】4
  • 【下载频次】151
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