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高性能NBR/PP热塑性硫化胶的制备与研究

Preparation and Study of NBR/PP Thermoplastic Vulcanizates

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【作者】 韩吉彬施凤莲田洪池伍社毛刘丽萍张立群

【Author】 HAN Jibin, SHE Fenglian, TIAN Hongchi, WU Shemao, LIU Liping, ZHANG Liqun of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, China)

【机构】 北京化工大学北京市新型高分子材料制备与加工重点实验室北京化工大学北京市新型高分子材料制备与加工重点实验室 北京 100029北京 100029北京 100029

【摘要】 研究了马来酸酐接枝聚丙烯(MP)、氯化聚丙烯(CPP)以及端胺基液体丁腈橡胶(ATBN)和马来酸酐接枝聚丙烯复合增容剂对NBR/PP共混体系的增容效果。采用溴化树脂体系、酚醛树脂体系和DCP体系,分别对共混体系的动态硫化效果进行了讨论。研究了DOP和聚酯对共混体系的增塑效果及耐油效果的影响。对TPV的相态结构、力学性能和耐热油性能研究表明:用ATBN/MP增容的共混体系经酚醛树脂动态硫化后,可以获得相态结构精细、性能优异的TPV;聚酯增塑剂是NBR/PP共混体系的一种比较理想的增塑剂。

【Abstract】 The effects of various compatibilizers, such as maleicmodified polypropylene(MP), chlorinated polypropylene(CPP), amineterminated liquid NBR(ATBN) and maleicmodified polypropylene(ATBN/MP)on NBR/PP blends system were investigated. The effects of dynamic vulcanization of NBR/PP blend were investigated in three kinds of vulcanization systems (sp1056, phenolic resin and DCP), respectively. And the effect of plasticization and hotoil resistance were also investigated with the introduction of plasticizer DOP and polyester into NBR/PP blend. The study on the morphology, mechanical properties and hotoilresistance properties showed that fine morphology and outstanding properties can be achieved when the blend was compatibilized by ATBN/MP and cured by phenolic resin; and polyester was a desired plasticizer for NBR/PP blend.

【基金】 国家自然科学基金资助项目(59903001)
  • 【文献出处】 特种橡胶制品 ,Special Purpose Rubber Products , 编辑部邮箱 ,2003年06期
  • 【分类号】TQ330
  • 【被引频次】20
  • 【下载频次】289
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