【摘要】 配合物稳定常数的应用日趋广泛，研究表明在相关联的配合物稳定常数间也存在定量的经验关系。通过配合物稳定常数间的直线自由能关系、logK与logKM(OH) 之间的线性关系、Irving-Williams 序列关系、稳定常数与Lewis酸碱参数的关系、镧系及锕系元素碳酸配合物稳定常数的计算等定量关系分析，表明溶液体系中配位化学的研究进展。更多还原

【Abstract】 By analyzing the quantitative relationships existing among stability constants, such as the Linear Free Energy Relationship (LFER), the linear relationship between logK and logKM(OH), irving-Williams order, the degree of stability constants relied on the acid-base parameter, and the stability constant’s computation of lanthanide and actinoid complexes containing carbonate ion, the advance in coordination chemistry in solution systems has been reviewed with 10 references.更多还原