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染料及表面活性剂的太阳光催化降解

Photocatalytic Decomposition of Dyes and Surfactant Under Solar Light Irradiation

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【作者】 张天永张友兰赵进才日高久夫

【Author】 ZHANG Tian yong, ZHANG You lan, ZHAO Jin cai, HIDAKA Hisao (1.School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China; 2.Institute of Chemistry, the Chinese Academy of Sciences, Beijing 100080, China; 3.Frontier Research Center for the Global Environmental Protection, Meisei University, Tokyo 191-8506, Japan)

【机构】 天津大学化工学院中国科学院化学研究所日本明星大学地球环境保护中心 天津300072天津300072北京100080东京191—8506

【摘要】 制作了一种聚集太阳光光催化反应装置,在纳米半导体TiO2存在下可用于净化染料和表面活性剂污染物,并可使其快速降解并矿化.含有N—甲基助色基团染料的降解伴随脱甲基过程,混合物最大吸收峰发生蓝移.总有机碳(TOC)值降低与污染物有关,当降解生成中间体与污染物有较强的竞争吸附时,TOC值有升高现象.对不同的污染物降解,有不同的较适宜的TiO2用量.

【Abstract】 A solar light concentrator for photocatalytic reaction was prepared, with which dyes and surfactant pollutants could be efficiently degraded and mineralized.Accompanied with mineralization, N-demethylation of dyes containing N-methyl groups occurred, and made the maximal absorption band of degraded mixtures hypsochromic effects. Elimination of total organic carbon (TOC) is related to the properties of pollutants degraded. The strong competitive adsorption between the pollutants and the formed intermediates lead to the temporal TOC increase. Various optimal TiO 2 loadings is corresponded to the different substrates decomposed.

【关键词】 光催化太阳光二氧化钛染料表面活性剂废水
【Key words】 photocatalysissolar lighttitanium dioxidedyesurfactantwastewater
【基金】 教育部留学回国人员科研启动基金资助项目.
  • 【文献出处】 天津大学学报 ,Journal of Tianjin University , 编辑部邮箱 ,2003年01期
  • 【分类号】X788
  • 【被引频次】34
  • 【下载频次】400
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