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超临界CO2萃取-分子蒸馏对白术挥发油的提取分离和GC-MS分析

Analysis of Essential Oil from Rhizoma Atractylodis Macrocephalae by GC-MS with Supercritical CO2 Extraction and Molecular Distillation

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【作者】 张忠义王鹏雷正杰吴惠勤

【Author】 ZHANG Zhong_yi 1 ,WANG Peng 1 ,LEI Zheng_jie 1 ,WUHui_qin 2 (1.Zhujiang Hospital,First Military Medical University,Guangzhou510282,China; 2.China National Analysis Center,Guangzhou510070,China)

【机构】 第一军医大学珠江医院中国广州分析测试中心 广东广州510282广东广州510282广东广州510070

【摘要】 用超临界CO2 萃取技术提取白术挥发油 ,然后用分子蒸馏对所得的萃取物进行精分离 ,得到蒸出物 ;超临界萃取物收率为2.42 % (w) ,分子蒸馏蒸出物收率26.3% (w) ;对超临界萃取物和分子蒸馏蒸出物分别进行GC -MS分析 ,结果超临界萃取物检测出33个化合物 ,分子蒸馏蒸出物检测出27个化合物 ,主要成分均为2,7甲氧基3,6甲基萘、γ子烯、大根香叶烯等 ,但相对含量有区别

【Abstract】 Essential oil from Rhizoma Atractylodis Macrocephalae was extracted by supercritical fluid extraction(SFE)and the extractive separated by molecular distillation(MD).The extraction yield of2.42%(w)and yield of distilled oil of26.3%(w)were obtained.The constituents of extractive and distilled oil were analyzed by gas chromatography-mass spectrometry.Thirtythree compounds from the extracttive and twentyseven compounds from the distilled oil were identified,and their relative contents were determined by normalization method of area.The major constituents of both have been found to be2,7dimethoxy3,6dimethyl naphthalene,γselinene and germacrene B etc.

【基金】 广东省科技攻关项目 (2KB01202S)
  • 【文献出处】 分析测试学报 ,Journal of Instrumental Analysis , 编辑部邮箱 ,2003年04期
  • 【分类号】O657.63
  • 【被引频次】82
  • 【下载频次】900
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