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Pt/H-SAPO-11催化剂用于重质油催化转化研究初探

INVESTIGATION ON CATALYTIC CONVERSION OF HEAVY OIL OVER Pt/H-SAPO-11 CATALYST

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【作者】 王祖鵷陈建王光维

【Author】 Wang Zuyuan, Chen Jian, Wang Guangwei(School of Chemical Engineering and Technology , Tianjin University , Tianjin 300072;Changchun Institute of Applied Chemistry , Chinese Academy of Sciences ; Department of Petroleum Chemical Engineering, Daqing Petroleum Institute)

【机构】 天津大学化工学院中国科学院长春应用化学研究所大庆石油学院石油化工系 天津 300072

【摘要】 应用SAPO-11分子筛负载Pt制备Pt/H-SAPO-11催化剂。以糠醛精制后的丙烷脱沥青油150BS为反应介质,在20mL催化加氢反应装置上对Pt/H-SAPO-11催化剂进行评价。考察在反应压力14.5MPa,氢油体积比700,质量空速1.35h-1,不同反应温度条件下反应产物的收率及大于370℃润滑油馏分凝点和粘度指数的变化。结果表明,小于200℃馏分油,200~315℃轻质燃料油馏分,315~370℃轻质润滑油馏分,以及大于370℃润滑油混合馏分等液体总收率保持在90%左右。大于370℃润滑油混合馏分的凝点可达-15℃,粘度指数为107。

【Abstract】 Pt/H-SAPO-11 catalyst was prepared by platinum carried on SAPO-11 molecular sieve. The catalyst was evaluated on a 20 mL hydrogenation unit with 150BS lube base oil, a propane deasphalted oil after furfural refining, as feedstock. The product yields, and the pour point and viscosity index of the lube fraction higher than 370℃ were investigated under a pressure of 14. 5MPa, a hydrogen/oil ratio volume ratio of 700 and a WHSV of 1. 35h-1 at different temperatures. The results showed that the sum of the yields of the <200℃ and 200-315℃ light fuel oils, the 315-370℃light lube oil and >370℃ lube fraction reached around 90%. The pour point and viscosity index of the >370℃ lube fraction was - 15℃ and 107 respectively.

【基金】 中国石油天然气集团公司科研项目990801—18
  • 【文献出处】 石油炼制与化工 ,Petroleum Processing and Petrochemicals , 编辑部邮箱 ,2003年06期
  • 【分类号】TE624
  • 【被引频次】2
  • 【下载频次】101
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