【摘要】 在冰醋酸中,用氯酸钠(氯酸钾),碘和盐酸能直接制得一氯化碘溶液.利用此溶液,在比较温和的条件下,无需经过复杂的过程,可使芳胺、苯氧乙酸碘化为相应的碘代芳香化合物.该溶液是一种反应条件温和,选择性比较好的芳环碘化剂.更多还原

【Abstract】 We can make sodium chlorate (or potassium chlorate) unite with iodine and chloride acid to yields iodine mono-chloride solution under acetic acid. Using this solution, we can use aromatic arming, salicylic acid and phenoxyacetic acid to iodo-substituted aromatic compounds relevantly in a mild condition and without complex process. This solution is a mild yet effective iodinating agent for active aromatic rings with good selectivity. 更多还原