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二苯基碳酰二肼光度法测定镀锌层中铬

Diphenlycarbazide Spectrophotometry

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【作者】 陈瑞兰刘英华徐引娟叶锦裔

【Author】 CHEN Ruilan1,LIU Yinghua2,XU Yinjuan1YE Jinyi1(1.School of Sciences, Shanghai University, Shanghai 200436, China;2.Nanhui Environmental Monitoring Station of Shanghai, Shanghai 201300, China)

【机构】 上海大学理学院上海南汇区环境监测站上海大学理学院 上海200436上海201300上海200436上海200436

【摘要】 研究了二苯基碳酰二肼与微量铬的显色反应,在硫酸介质中铬与二苯基碳酰二肼反应生成可溶性的紫红色络合物,在波长为550nm处测其吸光度.当铬含量在0~25μg/50mL范围内符合比尔定律,此法应用于铁片镀锌层中微量铬的测定获得满意结果.

【Abstract】 The color reaction of diphenlycarbazide and the microamounts of chromium are studied in the medium of sulfuric acid. A soluble purplish red complex is formed by this reaction, and absorbency of the colorful complex is determined at 550 nm. In the range of 0~25 μg/50 mL for chromium content, the results conform to Beer’s law. With this method, satisfactory results can be obtained in the determination of microamount of chromium in galvanized iron.

  • 【文献出处】 上海大学学报(自然科学版) ,Journal of Shanghai University(Natural Science Edition) , 编辑部邮箱 ,2003年01期
  • 【分类号】O657.3
  • 【被引频次】4
  • 【下载频次】119
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