【摘要】 在非水溶剂中用直接电化学方法合成了金属铜与2′ 羟基 5′ 甲基苯乙酮(HMAP)及三苯基膦(pph3)的三元配合物,产物经元素分析、拉曼光谱、核磁共振表征及合成过程电流效率测定,该配合物组成为(MAP)Cu(pph3)2,其中Cu和MAP 的两个氧原子配位形成一个五元环结构,同时还和两个中性三苯基瞵配位,形成金属Cu的一价配合物.还探讨了电合成条件,反应机理以及中性配体在低价配合物形成过程中的作用.更多还原

【Abstract】 The complex of Cu with 2′hydroxy5′methylacetophenone(HMAP) and triphenylphosphine (pph3) was prepared by the electrochemical oxidation in nonaqueous solution.The final product,(MAP)Cu(pph3)2 was characterized by electrochemical efficiency(Ef), microanalysis, Raman and1H NMR. The results show that the Cu(I) ion interact with both oxygen atoms of MAP-,H being removed from the ligand and a five member ring is formed. The condition of synthesis, the reaction mechanism on the electrode and the effect of pph3 on the stability of the complex are discussed.更多还原