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丙烯酸酯和马来酸酐二元共聚物及其醇解胺解的合成与表征

Synthesis and Characterization of the Bipolymer or Alcoholysis Aminate of the Acrylic Alkyl Ester and Maleic Anhydried

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【作者】 薛兆民李伟男梁广伦

【Author】 XUE Zao-min,LI Wei-nan,LIANG Guang-lun(Chemistry Department of Heze Teachers College,Heze 274015,China)

【机构】 山东菏泽师专化学系山东菏泽师专化学系 山东菏泽274015山东菏泽274015山东菏泽274015

【摘要】 主要介绍了丙烯酸酯和马来酸酐二元共聚物 (简称AM )及其醇解胺解物 (简称AM -a)类柴油降凝剂的合成、表征和降凝助滤效果 ,AM -a柴油降凝剂 ,是以丙烯酸酯、马来酸酐为原料 ,以甲苯为溶剂 ,以偶氮二异丁腈为引发剂 ,恒温聚合成AM ,再以对甲苯磺酸为催化剂 ,用高碳醇及高碳胺进行醇解及胺解而制得 ,该剂对东明 0 #柴油的纯降凝度可达 16℃ ,冷滤点降低可达 8℃ ,对汤阴 10 #柴油的纯降凝度可达 14℃ ,冷滤点降低可达 6℃。

【Abstract】 The synthesis,characterization,the effect of SP and CFPP depressed for diesel fuels of the depressant of the bipolymer(or AM) of alcoholysis aminatc(or AM-a) of the acrylic alkyl ester and maleic anhydride are mainly introduced in the article.The AM-a depressant was produced by using acrylic alkyl ester and maleic anhydride as raw materials,methyl benzene as solvents,azobisisobutyronitrile as initiator,bipolymer(AM) by constant temperature polymerization,second p-methyl benzene sulfonic acid as catalyst,higher alcohols and amine as alcoholate and aminating agent.The depressant was applied for the 0 #diesel fuels from Dongming,the SP (solidifying point) of the 0 # diesel fuels was lowered by 16℃ and the CFPP (cold filter plugging point) 8℃.The SP of he 10 # diesel fuels from Tangyin was lowered by 14℃ and the CFPP 6℃.

【基金】 山东省科技厅自然科学基金资助项目 (9912 2 6 30 7)
  • 【文献出处】 山东化工 ,Shandong Chemical Industry , 编辑部邮箱 ,2003年05期
  • 【分类号】TE624.8
  • 【被引频次】10
  • 【下载频次】547
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