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乙醇在碳载纳米Pt及纳米Pt-WO3电极上的催化氧化

ELECTROCATALYTIC OXIDATION OF ETHANOL ON THE NANO-Pt/GC ELECTRODE AND THE NANO-Pt-WO3/GC ELECTRODE

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【作者】 李小芳张亚利孙典亭

【Author】 LI Xiao-fang,ZHANG Ya-li ,SUN Dian-ting (College of Chemical Engineering, Qingdao Univerity, Qingdao 266071,China)

【机构】 青岛大学化工学院青岛大学化工学院 山东青岛266071山东青岛266071山东青岛266071

【摘要】 将纳米Pt/玻碳和纳米Pt -WO3 /玻碳电极应用于乙醇的电催化氧化 ,发现所制备的催化剂电极具有较高的电催化活性。探讨了乙醇在这些电催化电极上的循环伏安曲线中各个峰产生的原因

【Abstract】 The nano-Pt/GC electrode and the nano-Pt-WO 3/GC electrode prepared by electrochemical cyclic voltammetry and constant potential deposition techniques respectively, have been applied to the electrocalalytic oxidation of ethanol. The results show that the two electrodes both exhibit the high electro-catalytic activity, and the nano-Pt-WO 3/GC electrode is higher than nano_Pt/GC.The apparent current density of nano-Pt-WO 3/GC electrode is ca. 10 times higher than the nano-Pt/GC electrode; the mass current density of nano-Pt/GC electrode is ca.5 orders of magnitude higher than the Pt electrode. The origin of various peaks in relation to the oxidation of ethanol species is also explained.

【基金】 中科院应化所国家开放实验室基金;青岛大学校科研基金资助
  • 【文献出处】 青岛大学学报(自然科学版) ,Journal of Qingdao University(Natural Science) , 编辑部邮箱 ,2003年01期
  • 【分类号】O646.5
  • 【被引频次】11
  • 【下载频次】149
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