节点文献
一种新奇的Ru(Ⅱ)配合物[Ru(bpy)3](dca)I0.5(OH)0.5·3H2O的合成与晶体结构(英文)
SYNTHESIS AND CRYSTAL STRUCTURE OF A NOVEL RUTHENIUM(Ⅱ) COMPLEX [Ru(bpy)3](dca) I0.5(OH)0.5 ·3H2O (dca = DIC Y AN AMIDE, N (CN)2; bpy = 2,2’ -BIP YRIDINE)
【摘要】 合成了一种新奇的Ru(Ⅱ)配合物[Ru(bpy)3](dca)I0.5(OH)0.5·3H2O并进行了结构表征,该化合物属于六方晶系,P6/mcc晶胞群,晶格参数为a=1.3505(3)nm,b=1.3505(3)nm,c=2.1263(6)nm,α=90°,β=90°,γ=120°.在该化合物中,配体bpy和OH-离子之间以及dca和结晶水之间都存在较强的氢键作用。
【Abstract】 A novel Ruthenium(Ⅱ) complex [Ru(bpy)3](dca)I0.5(OH)0.5·H2O has been synthesized and structurally characterized. This complex crystallize in the hexagonal, space group P6/mcc with a= l.3505(3) nm,b=1.3505(3)nm,c = 2. 1263(6)nm,α=90°β=90°γ= 120°.In this complex, bpy, OH- ion, dca and the uncoordinated water molecules are all involved in H-bonding interactions.
【基金】 Supported by the National Natural Science Foundation of China(20071019,50172021,90101028)
- 【文献出处】 南开大学学报(自然科学版) ,Acta Scientiarun Naturaltium Universitatis Nankaiensis , 编辑部邮箱 ,2003年04期
- 【分类号】O641.4
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