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P204萃取分离锑铁工艺研究
Technology Study on Separation Fe from HCl-NH4Cl-SbCl3 Solution by P204
【摘要】 萃取分离锑铁是脆硫锑铅矿矿浆电解工艺过程的一个环节。P2 0 4可选择性地在NH4 Cl介质溶液中萃取铁。在 35 %(体积百分数 )P2 0 4、相比 (O/A) 1∶1、3级连续逆流萃取条件下 ,铁萃取率达 80 %~ 84%,锑、银基本不被萃取。含Fe总 1~ 1 4g/L的萃余液可返回矿浆电解循环使用。
【Abstract】 Using solvent extraction to separate Fe from HCl-NH 4Cl-SbCl 3 solution is a section in the process of Slurry Electrolysis to treat jamesonite. P204 can extract ferric ions from HCl-NH 4Cl solution selectively. Test results show that the Fe extraction ratio reaches to more than 80% by using 35 % (volume percentage) P204 in the condition of O/A=1:1 and 3 stages anti-current extraction. Sb and Ag remain in raffinate. The raffinate with 1~1.4 g/L Fe can be recirculated to slurry electrolysis.
【关键词】 锑;
铁;
溶剂萃取;
P204萃取剂;
矿浆电解;
【Key words】 Antimony; Iron; Solvent extraction; P204 reagent; Slurry electrolysis;
【Key words】 Antimony; Iron; Solvent extraction; P204 reagent; Slurry electrolysis;
- 【文献出处】 有色金属(冶炼部分) ,Nonferrous Metals , 编辑部邮箱 ,2003年02期
- 【分类号】TF818
- 【被引频次】11
- 【下载频次】330