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Al<sub>2O3-MgO·1.35Al2O3复合浆料的流变特性研究

Study on rheological behavior of Al2O3-MgO·1.35Al2O3 suspensions

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【作者】 刘开琪宋慎泰李林洪彦若孙加林

【Author】 Liu Kaiqi,Song Shentai,Li LinAuthor’s aadress:Inorganic Non ferrous Materials Department,University of Science and Technology Beijing,Beijing 100083,China

【机构】 北京科技大学无机非金属材料系钢铁研究总院九室北京科技大学无机非金属材料系 北京100083钢铁研究总院九室北京100083北京100083

【摘要】 测试了高纯板状刚玉粉 (Al2 O3)、富铝尖晶石粉 (MgO·1 .35Al2 O3)及其复合粉料 (Al2 O3-MgO·1 .35Al2 O3)在水溶液中不同 pH值下的ζ电位 ,三者的等电点分别为 7.4、~ 3和 5 .3。研究了分散剂三聚磷酸钠对复合浆料的ζ电位和流动性的影响 ,结果表明 :外加 1wt%溶剂量的三聚磷酸钠可降低复合浆料的ζ电位约 40mV ;制备Al2 O3-MgO·1 .35Al2 O3复合浆料的理想 pH值范围为 9~ 1 1 ;复合浆料中MgO·1 .35Al2 O3对流变特性的影响比Al2 O3的大。

【Abstract】 The zeta potentials of high purity tabular alumina(Al 2O 3),alumina rich spinel(MgO·1.35Al 2O 3) and their mixture Al 2O 3-MgO·1.35Al 2O 3 at different pH values were measured.The results reveal that the isoelectric points(IEP) of Al 2O 3,MgO·1.35Al 2O 3 and Al 2O 3-MgO·1.35Al 2O 3 suspensions are 7.4,~3.0 and 5.3.The influence of dispersant sodium tripolyphosphate(STP) on the zeta potential and flow value of binary suspension was investigated.By adding 1wt% STP in the solvent,the zeta potential of the binary suspensions can be reduced 40 mV on average.The optimum pH value range for preparing the binary aqueous suspensions is between 9 and 11.Influence of MgO·1.35Al 2O 3 on rheological behavior of the binary suspensions is bigger than that of tabular alumina.

  • 【分类号】TQ175.73
  • 【被引频次】3
  • 【下载频次】107
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