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锗的地球化学性质与锗矿床

A Review of Disperse Element Germanium

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【作者】 章明顾雪祥付绍洪司荣军李发源

【Author】 ZHANG Ming1,2, GU Xuexiang2, Fu Shaohong1,2, SI Rongjun2, LI Fayuan1,21. Chengdu University of Technology, Chengdu 610059, China;2. Institute of Geochemistry, Chinese Academy of Sciences,Guiyang 550002, China

【机构】 成都理工大学中国科学院地球化学研究所矿床地球化学开放研究实验室成都理工大学 成都610059贵阳550002成都610059贵阳550002

【摘要】 锗具有亲石、亲铁、亲硫和亲有机质等多重地球化学性质,岩浆作用不能使锗发生明显富集,但锗可富集在一些花岗伟晶岩矿物中,只有热液体系才能大量搬运锗,在表生溶液中具有较高的活动性,属于过渡类的分散元素。世界上已发现26个锗矿物。锗矿床可分为伴生锗矿床和独立锗矿床两大类。锗与其它分散元素具有普遍的共生关系,与镓的共生尤为密切;锗对环境的危害物主要为Ge金属、GeH4、GeO2和GeCl4;并综述了锗的主要工业来源及市场应用现状。

【Abstract】 This paper simply generalizes germanium’s physical and chemical characters, and lists 26 germanium minerals which have been reported in literatures. Ge is a lithophile,siderophile,sulphophile element and also easy to combine with organic matter, can not be concentrated in magma process, but can be enriched in some granitepegmatite minerals. Ge belongs to one of disperse transitional elements,is fairly active in solution and can be transferred greatly only in hydrothermal fluid system. The paper discusses the Ge deposit types and gives a simplified definition for independent Ge deposit. Ge coexists with many other disperse elements, especially with Ga. The harmful occurence modes of Ge are Ge metal, GeH4, GeO2 and GeCl4. Finally the paper discusses the main industrial source and present market consumption of Ge. 

【基金】 国家自然科学基金(49872038);中国科学院"百人计划"项目资助
  • 【文献出处】 矿物岩石地球化学通报 ,Bulletin of Mineralogy Petrology and Geochemistry , 编辑部邮箱 ,2003年01期
  • 【分类号】P595
  • 【被引频次】42
  • 【下载频次】659
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