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DMPA聚氨酯乳液的制备和性能

Preparation and Properties of Polyurethane Emulsion from DMPA

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【作者】 朱立华张剑秋

【Author】 ZHU Lihua1,ZHANG Jianqiu2(1. School of Materials Science and Engineering, Tongji University, Shanghai 200092, China;2. College of Environment and Chemical Engineering, Shanghai University, Shanghai 200072, China)

【机构】 同济大学材料科学与工程学院上海大学环境与化学工程学院 上海200092上海200072

【摘要】 用聚醚,TDI,1,4 丁二醇和二羟甲基丙酸(DMPA)等制备了聚氨酯乳液,引入的DMPA作为阴离子亲水基团,使PU具有了亲水性.讨论了合成过程中的一些影响因素和胶乳的稳定性.结果表明:选择合适的DMPA加入方式,对胶乳的稳定性影响很大.增加DMPA用量,可使胶乳的粒径减小,乳液的稳定性提高;用固化剂(AQ 100)固化以后,产品有较好的强度.

【Abstract】 Polyurethane emulsion was prepared from polyether, TDI, 1,4butanediol and DMPA. The ionic hydrophilic groups was introduced in the polyurethane chain to get the waterborne polyurethane. The factors which had effect on the synthesis and quality of PU emulsion were investigated. The results show that the ways by which DMPA is put into resin and the amounts of the DMPA added have effect on the stability of the emulsion. The product cured with AQ100 curing agent has the high strength.

【关键词】 亲水基DMPA聚氨酯乳液
【Key words】 hydrophilic groupDMPApolyurethane emulsion
【基金】 上海市教委自然科学研究资助项目(2000A34)
  • 【文献出处】 建筑材料学报 ,Journal of Building Materials , 编辑部邮箱 ,2003年01期
  • 【分类号】TQ323
  • 【被引频次】15
  • 【下载频次】418
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