节点文献

一维链状高价锰配合物[Mn₂（C₇H₄O₃）₄（CH₃OH）₂]·4H₂O₂CH₃OH的合成与结构

Synthesis and Crystal Structure of One Dimensional Chain Manganese Complex [Mn₂（C₇H₄O₃）₄（CH₃OH）₂]·4H₂O₂CH₃OH

推荐 CAJ下载
PDF下载
不支持迅雷等下载工具，请取消加速工具后下载。

【Author】 LI Juna ZHANG Feng-Xinga WU Ai-Zhia SHI Qi-Zhena LI Yi-Zhib WANG Liu-Fangb a(Chemistry Department, Shanxi Key Laboratory of Phosico-Inorganic Chemistry, Northwest University, Xi抋n 710069, China) b(Chemistry Department, Lanzhou Universtry, Lanzhou 730000, China)

【机构】西北大学化学系陕西省物理无机化学重点实验室；兰州大学化学与化工学院；兰州大学化学与化工学院西安710069；西安710069；兰州730000；兰州730000；

【摘要】合成了一维链状高价锰配合物[Mn2(C7H4O3)4(CH3OH)2]4H2O2CH3OH,并对其进行了IR、X-射线衍射、UV-Vis和TG-DSC等表征。单晶衍射结果表明,该配合物晶体属三斜晶型,空间群P?晶胞参数a=7.653(5),b=10.486(7),c=12.943(8),=103.24(1),?=104.55(1),?=110.11(1),V=885.4(9)3,Z=1。UV-Vis光谱在547nm有一个吸收峰,相应于Mn(Ⅳ)的d-d电子跃迁光谱。更多还原

【Abstract】 The one dimensional chain manganese complex [Mn2(C7H4O3)4(CH3OH)2]4H2O2CH3OH has been synthesized, and it was characterized by IR, X-ray diffraction and UV-Vis. X-ray diffraction result shows that the crystal belongs to triclinic, space group P with a = 7.653(5), b = 10.486(7), c = 12.943(8) ,?= 103.24(1), ?= 104.55(1), ?= 110.11(1)? V = 885.4(9) 3 and Z = 1. UV-Vis spectrum result indicates there exists a peak at 547 nm, corresponding to the electron transition of d-d.更多还原