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铬铁矿在熔融滴下过程中的还原机理

Reduction Mechanism of Chromite Ore during Smelting Dropping

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【作者】 李一为丁伟中游锦洲郑少波鲁雄刚徐建伦徐匡迪

【Author】 LI Yiwei, DING Weizhong, YOU Jinzhou, ZHENG Shaobo, LU Xionggang, XU Jianlun, XU Kuangdi (Shanghai University, Shanghai 200072, China)

【机构】 上海大学上海市钢铁冶金重点实验室上海大学上海市钢铁冶金重点实验室 上海200072上海200072上海200072

【摘要】 为了探讨铬铁矿的熔融还原机理,利用光学显微镜、电子扫描显微镜和能谱分析技术,观察分析熔融滴下实验中不锈钢母液炉料滴下物的结构形态变化。结果表明,还原过程可分为两个阶段:首先是铬铁矿通过CO气体的间接还原,其还原机理可用未反应核模型解释;其后是铬铁矿逐步在渣相中溶解,被固体碳直接熔融还原。

【Abstract】 The structure change of chromite during smelting dropping of crude stainless steel was studied by means of optical micrograph analysis, scanning electron microscope (SEM) and energy dispersive Xray analysis (EDAX). The smelting reduction mechanism of chromite was primarily discussed. The results show that the process of reduction occurs in two stages. At the first stage, the chromite ore is reduced indirectly with CO, which can be described well by the unreacted core model. The second stage is involved in the dissolution of chromite ore into the slag, and the direct smelting reduction is initiated by solid carbon.

【关键词】 熔融还原铬铁矿机理
【Key words】 smelting reductionchromite oremechanism
【基金】 国家自然科学基金资助项目(50174036)
  • 【文献出处】 钢铁研究学报 ,Journal of Iron and Steel Research , 编辑部邮箱 ,2003年06期
  • 【分类号】TF557
  • 【被引频次】5
  • 【下载频次】324
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