节点文献

Synthesis of Chiral Aminophenols Based on Proline and Their Application in Enantioselective Addition of Diethylzinc to Aldehydes

Synthesis of Chiral Aminophenols Based on Proline and Their Appli-cation in Enantioselective Addition of Diethylzinc to Aldehydes

推荐 CAJ下载
PDF下载
不支持迅雷等下载工具，请取消加速工具后下载。

【Author】 GE, Jian-Feng SHEN, Zong-Xuan ZHANG, Ya-WenLU, Xin-Hua LU, Zhong-E Department of Chemistry and Chemical Engineering , Suzhou University, Suzhou , Jiangsu 215006, China Department of Material and Engineering , Suzhou University, Suzhou, Jiangsu 215006, China

【机构】 Dapartment of Chemistry and Chemical Engineering； Suzhou University； Suzhou； Jiangsu 215006； China Department of Material and Engineering； China； Department of Chemistry and Chemical Engineering； China；

【摘要】 <正> Three 2-{(3R,7As)-1,1-disubstituted-tetrahydro-1 H-pyrrolo[1,2-c][1,3]oxazol-3-yl}phenols have been synthesized fromsalicylaldehyde and amino alcohols derived from L-proline,andused as ligands in enantioselective addition of diethylzinc toaldehydes,the ee values of obtained secondary alcohols werefound in the range of 0-90%.更多还原

【Abstract】 Three 2-{(3R, 7aS)-1, 1-disubstituted-tetrahydro-1H-pyrrolo [1,2-c][1,3]oxazol-3-yl} phenols have been synthesized from salicylaldehyde and amino alcohols derived from L-proline, and used as ligands hi enantioselective addition of diethylzinc to aldehydes, the ee values of obtained secondary alcohols were found in the range of 0-90%.更多还原

【关键词】 aminophenol； 2-{(3R； 7aS )-1； 1-disubstituted-tetrahydro-1H-pyrrolo[1； 2-c][1； 3]oxazol-3-yl}-phenols； enantio-selective addition； diethylzinc；
【Key words】 aminophenol； 2-{(3R； 7aS )-1； 1-disubstituted-tetrahydro-1H-pyrrolo[1； 2-c][1； 3]oxazol-3-yl}-phenols； enantio-selective addition； diethylzinc；

【基金】 Project supported by the Key Laboratory of Organic Syntheses,Jiangsu Province(No.T2109102).

【文献出处】 Chinese Journal of Chemistry ,中国化学(英文版) , 编辑部邮箱 ,2003年07期

【分类号】O623
【下载频次】3

知网节下载

节点文献中：

本文链接的文献网络图示:

本文的引文网络

节点文献