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Enhancive Synthesis of (±)-1β,11-Diol-4-en-eudesmol
【摘要】 <正> An enhancive synthesis of (±)-1β, 11-diol-4-en-eudesmol,starting from 2-chloroacrylonitrile, is described. The effect oftemperature on the Diels-Alder reaction of 2-chloroacrylonitrilewith 2-methylfuran and the condition of cationic cyclization ofdiene were discussed in detail.
【Abstract】 An enhancive synthesis of (±)-1β, 11-diol-4-en-eudesmol, starting from 2-chloroacrylonitrile, is described. The effect of temperature on the Diels-Alder reaction of 2-chloroacrylonitrile with 2-methylfuran and the condition of cationic cyclization of diene were discussed in detail.
【关键词】 Diels-Alder reaction；
cationic cyclization；
eudes-mane；
sesquiterpenoids；
【Key words】 Diels-Alder reaction； cationic cyclization； eudes-mane； sesquiterpenoids；
【Key words】 Diels-Alder reaction； cationic cyclization； eudes-mane； sesquiterpenoids；
【基金】 Project supported by the National Natural Science Foundation of China(No.20272021).
- 【文献出处】 Chinese Journal of Chemistry ,中国化学(英文版) , 编辑部邮箱 ,2003年07期
- 【分类号】O621
- 【下载频次】4