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Catalytic Asymmetric [2, 3]-Sigmatropic Rearrangement of Sulfur Ylides Generated from Carbenoids and Allenic 2-Methylphenyl Sulfide

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【Author】 ZHANG, Xiao-Mei MA, Ming WANG, Jian-Bo Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education , Department of Chemical Biology , College of Chemistry, Peking University, Beijing 100871, China State Key Laboratory of Elemento- Organic Chemistry, Nankai University , Tianjin 300071, China

【机构】 Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education； Department of Chemical Biolegy； College of Chemistry； Peking University； Beijing 100871； China； Department of Chemical Biology； College of Chemistry； China State Key Laboratory of Elemento-Organic Chemistry； Nankai University； Tianjin 300071； China；

【摘要】 <正> The first investigation on catalytic asymmetric [2, 3]-sigmatrop-ic rearrangement of sulfur ylides generated from carbenoids andallenic phenyl sulfide was carried out. Up to 55% ee value wasobtained.更多还原

【Abstract】 The first investigation on catalytic asymmetric [2,3]-sigmatrop-ic rearrangement of sulfur ylides generated from carbenoids and allenic phenyl sulfide was carried out. Up to 55% ee value was obtained.更多还原

【关键词】 carbenoid； sulfur ylide； [2； 3 ]-sigmatropic rear-rangement； catalytic asymmetric synthesis；
【Key words】 carbenoid； sulfur ylide； [2； 3 ]-sigmatropic rear-rangement； catalytic asymmetric synthesis；

【基金】 Project supported by the National Natural Science Foundation of China(Nos.20225205 and 20172002),State Key Laboratory of Elemento-Organic Chemistry of Nankai University and by Trans-Century Training Programme foundation for the Talents by Ministry of Edu

【文献出处】 Chinese Journal of Chemistry ,中国化学(英文版) , 编辑部邮箱 ,2003年07期

【分类号】O643.3
【被引频次】5
【下载频次】1

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