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Stereoselective Synthesis of (E)-and (Z)-1,2-Disubstituted Ethene from Polymer-Supported Vinylic Selenide

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【Author】 SHENG, Shou Ri a,b HUANG, Xian ,a,c a Department of Chemistry, Zhejiang University (Xixi Campus), Hangzhou, Zhejiang 310028, China b Department of Chemistry, Jiangxi Normal University, Nanchang, Jiangxi 330027, China c State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

【机构】 Department of Chemistry,Zhejiang University (Xixi Campus),Department of Chemistry,Zhejiang University (Xixi Campus) Hangzhou, Zhejiang 310028,China； Department of Chemistry,Jiangxi Normal University, Nanchang,Jiangxi 330027,China,Hangzhou, Zhejiang 310028,China； State Key Laboratory of Organometallic Chemistry,Shanghai Institute ofOrganic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China；

【Abstract】 This letter describes a method for the stereoselective synthesis of polymer supported vinylic selenides and their applications to synthesis of ( E ) and ( Z ) 1,2 disubstituted ethenes on solid phase by the coupling reaction with Grignard reagents under the catalysis of NiCl 2(PPh 3) 2.更多还原

【关键词】 solid phase organic synthesis； polymer supported vinylic selenide； stereoselective synthesis； 1； 2 disubstituted ethene$$$$；
【Key words】 solid phase organic synthesis； polymer supported vinylic selenide； stereoselective synthesis； 1； 2 disubstituted ethene$$$$；

【基金】 theNationalNaturalScienceFoundationofChina (No .2 993 2 0 2 0 )

【文献出处】 Chinese Journal of Chemistry ,中国化学(英文版) , 编辑部邮箱 ,2003年04期

【分类号】O634
【下载频次】6

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