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四苯硼钠在活性炭表面吸附过程的疏水相互作用

Hydrophobic interaction for the adsorption of sodium tetraphenylborate onto activated carbon

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【作者】 于玲王晓玲邹立壮支献华朱书全

【Author】 YU Ling,WANG Xiao-ling,ZOU Li-zhuang,ZHI Xian-hua,ZHU Shu-quan(School of Chemical and Environmental Engineering, China University of Mining and Technology,Beijing 100083,China)

【机构】 中国矿业大学化学与环境工程学院中国矿业大学化学与环境工程学院 北京100083 山东莘县师范学校北京100083北京100083

【Abstract】 In this paper,the adsorption characteristics of sodium tetraphenylborate(NaBPh4)on activated carbon at 298.2,303.2,308.2,313.2 and 323.2 K was studied.The results show that the adsorption isotherm of NaBPh4 on activated carbon at different temperatures could be described using Langmuir equation.Furthermore,the standard Gibbs energy,enthalpy,entropy and hydrophobic interaction Gibbs energy for the adsorption of NaBPh4 on activated carbon were studied,and the result shows that the hydrophobic interaction of BPh-4 ion plays the most important role for the transfer of NaBPh4 from water to activated carbon surface.

  • 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2003年06期
  • 【分类号】O647.3
  • 【被引频次】1
  • 【下载频次】114
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