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四苯硼钠在活性炭表面吸附过程的疏水相互作用
Hydrophobic interaction for the adsorption of sodium tetraphenylborate onto activated carbon
【Abstract】 In this paper,the adsorption characteristics of sodium tetraphenylborate(NaBPh4)on activated carbon at 298.2,303.2,308.2,313.2 and 323.2 K was studied.The results show that the adsorption isotherm of NaBPh4 on activated carbon at different temperatures could be described using Langmuir equation.Furthermore,the standard Gibbs energy,enthalpy,entropy and hydrophobic interaction Gibbs energy for the adsorption of NaBPh4 on activated carbon were studied,and the result shows that the hydrophobic interaction of BPh-4 ion plays the most important role for the transfer of NaBPh4 from water to activated carbon surface.
【关键词】 四苯硼钠;
活性炭;
吸附等温线;
吸附热力学函数;
疏水作用;
【Key words】 sodium tetraphenylborate; activated carton; adsorption isotherm; thermodynamic property of adsorption; hydrophobic interaction;
【Key words】 sodium tetraphenylborate; activated carton; adsorption isotherm; thermodynamic property of adsorption; hydrophobic interaction;
- 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2003年06期
- 【分类号】O647.3
- 【被引频次】1
- 【下载频次】114