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醋酸基体浓度变化对元素ICP-MS行为的影响

The effects of different concentration of acetic acid matrix in ICP-MS

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【作者】 胡兆初胡圣虹刘勇胜林守麟

【Author】 HU Zhaochu1,HU Shenghong1,LIU yongSheng1,LIN SouLin2(1.Faculty of Earth Science,China Vniversity of Geosccences,Wuhan 430074,China;2.Faculty of Material Science and Chemical Engineering,China University of Geosciences,Wuhan 430074,China)

【机构】 中国地质大学地球科学院中国地质大学材料科学与化学工程学院 湖北武汉 430074湖北武汉 430074湖北武汉 430074

【Abstract】 The influence of different concentrations of acetic acid matrix on elemental ICP-MS signal was investigated.The analyte signal intensities were suppressed with higher concentration of acetic acid.However,signal enhancements occur under certain conditions.The matrix inducedchanges are highly dependent on the nebulizer gas flow rate and power.Higher concentration of acetic acid is thought to contribute to local cooling in the central channel of the plasma.As the concentration of acetic acid increases from 2% to 5%,analyte signal intensities decrease and oxide ratio increase,especial in the high nebulizer gas flow rate.Higher incident power and low nebulizer gas flow rate can allow the plasma to accept a change in the concentration(2% to 5%)of acetic acid without significant change analyte signal.

【关键词】 电感耦合等离子体质谱有机基体醋酸
【Key words】 ICP-MSorganic matrixacetic acid
【基金】 国家自然科学基金(49973026);壳幔体系开放研究实验室基金资助。
  • 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2003年01期
  • 【分类号】O657.63
  • 【被引频次】5
  • 【下载频次】140
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