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钇对掺铒多孔硅体系1.54μm发光的增强作用
Enhanced 1.54 μm Luminescence from Erbium and Yttrium Co-doped Porous Silicon
【摘要】 首次报道了用恒电位电解法将铒、钇共掺入多孔硅 (poroussilicon ,PS)中 ,经高温退火处理后 ,观察到了在近红外区(1 5 4μm)室温下较强的光致发光 (photoluminescence ,PL) ,并与掺铒多孔硅 (erbium dopedporoussilicon ,PS∶Er)做了比较 ,发现钇的共掺入对掺铒多孔硅体系 1 5 4μm发射起了增强作用 .研究了铒、钇共掺杂多孔硅 (erbiumandyttriumco dopedporoussilicon ,PS∶Er ,Y)光致发光强度随温度的变化 ,发现PS∶Er与Si∶Er材料相似 ,有较强的温度猝灭效应 ,而PS∶Er ,Y体系的PL强度随温度升高趋于平稳 ,且有增强的趋势 ,受温度影响不明显 ,并初步探讨了其发光机制 .
【Abstract】 Fabrication of erbium (Er) and yttrium (Y) co-doped porous silicon (PS∶Er,Y) is firstly reported. Enhancement of Er-related photoluminescence at 1.54 μm has been achieved by the co-doping of Y 3+ . The dependence of photoluminescence intensity on temperature was investigated. Luminescence quenching was observed for PS∶Er, similar to that for Si∶Er, while 1.54 μm luminescence intensity from PS∶Er,Y was found to increase a little when the photoluminescence spectra were measured at a higher temperature. A possible enhanced photoluminescence mechanism was proposed.
【Key words】 porous silicon; erbium; yttrium; co-doping; near infrared photoluminescence;
- 【文献出处】 化学学报 ,Acta Chimica Sinica , 编辑部邮箱 ,2003年09期
- 【分类号】O482.31
- 【被引频次】6
- 【下载频次】95