【摘要】 在室温 ,紫外光照下溶液相中C60 与聚苯乙烯的直接反应合成得聚苯乙烯的C60 加合物 .衍生物中C60 的含量可由C60的投料比来控制 .得到的产物经UV Vis ,FTIR ,GPC ,TGA及DSC等波谱表征 ,测得产物的分子量比母体聚苯乙烯的分子量稍高 .对溶液相的反应进行了现场的ESR研究 ,得到强的PSC-·60 的自由基信号 ,g值为 2 .0 0 2 4.同时对C60 和聚苯乙烯混合物固相体系的光照反应进行了ESR测试 .结果表明在反应过程中及最终产物中均存在稳定的C60 高分子链烃基自由基阴离子RC-·60 .表明了反应的自由基机理更多还原

【Abstract】 The C 60 chemically modified polystyrene derivatives were synthesized by direct reaction of a benzene solution of polystyrene and C 60 using UV irradiation at room temperature. The extent of fullerenation can be controlled by varying the C 60 feed mass ratio. The products were characterized by UV Vis, FTIR, GPC, TGA and DSC techniques. The molecular weights of the C 60 polystyrene derivatives were higher than those of the parent polystyrene. The reaction of C 60 with polystyrene in benzene solution was monitored by electron spin resonance (ESR) spectrum. An intense signal of stable free radical PSC -· 60 was observed with a g value of 2.0024. The ESR measurement also was performed in quartz ESR tubes containing a polystyrene/C 60 solid mixture under UV irradiation. All of the samples gave an ESR signal of fullerene polystyrene radical PSC -· 60 , and some ESR signals remained in final solid C 60 PS product after precipitation and drying in air. These results indicated the radical mechanism of the reaction.更多还原