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新型正充电单层结构有机光受体的研制

Preparation of a Novel Single-layer Positive-charged Photoreceptor

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【作者】 岳双林王远张鑫然黄煜王平桂琳琳唐有祺

【Author】 YUE, Shuang-Lin a,b WANG, Yuan , b ZHANG, Xin Ran b HUANG, Yu b WANG, Ping a GUI, Lin Lin b TANG, You Qi b ( a College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029) ( b State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Physical Chemistry, Peking University, Beijing 100871)

【机构】 北京化工大学化学学院北京大学物理化学研究所分子动态与稳态结构国家重点实验室北京大学物理化学研究所分子动态与稳态结构国家重点实验室 北京100029北京大学物理化学研究所分子动态与稳态结构国家重点实验室北京100871北京100871北京100029北京100871

【摘要】 将纳米级酞菁氧钒分散于聚碳酸酯成膜剂中 ,成功研制了一类性能优良的单层结构有机光受体 .实验结果表明此类光受体随着酞菁氧钒在聚碳酸酯中含量的变化 ,其灵敏度、暗衰、饱和电位及残余电位出现规律性变化 .控制酞菁氧钒在聚碳酸酯中的含量可使此类光受体表现出优良的电荷保持能力 ,并在可见至近红外光谱范围内具有高灵敏度、低暗衰和低残留电位 .当酞菁氧钒含量为 3 2 %时 ,光受体的光衰灵敏度 (曝光波长 780nm ,光强 1.17μW )E1/ 2 =1.13 μJ/cm2 ,E1/ 5=1.2 1μJ/cm2 ,充电电位V0 =62 3V ,暗衰DD =2 4.5V/s ,残余电位VR=12V .

【Abstract】 A novel single layer, positive charged photoreceptor with excellent photoconductive properties was prepared by dispersing nanoparticles of vanadyl phthalocyanine with average size of 2.4 nm in polycarbonate resin. Influences of the content of vanadyl phthalocyanine on the sensitivity ( E 1/2 ), dark decay ( DD ), charged potential ( V 0) and residual voltage ( V R) of the prepared photoreceptors were studied. When the vanadyl phthalocyanine content in polycarbonate resin was properly controlled, single layer photoreceptors with high charged potential, good photosensitivity, low dark decay and residual voltage were obtained. Photoconductivities of a prepared photoreceptor having 32% of vanadyl phthalocyanine nanoparticles in polycarbonate resin are listed as follows: E 1/2 (exposure light: 780 nm, 1.17 μW)=1.13 μJ/cm 2, E 1/5 =1.21 μJ/cm 2, V 0 =623 V, DD = 24.5 V/s and V R=12 V.

【基金】 国家杰出青年科学基金 (No.2 992 530 8);国家重点基础发展规划 (No.2 0 0 0 0 7750 3)资助项目
  • 【文献出处】 化学学报 ,Acta Chimica Sinica , 编辑部邮箱 ,2003年04期
  • 【分类号】TN256
  • 【被引频次】1
  • 【下载频次】80
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