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Pd催化剂在甲醇裂解中的应用研究进展

The Research Advances in Supported Palladium Catalysts for Methanol Decomposition

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【作者】 彭必先甘昌胜闫天堂

【Author】 Peng Bixian, Gan Changsheng #, Yan Tiantang # (Technical Institute of Physics and Chemistry,Chinese Academy of Sciences,Beijing 100101; #School of Chemistry and Material Science,University of Science and Technology of China,Hefei 230026,China)

【机构】 中国科学院理化技术研究所中国科学技术大学化学与材料科学学院中国科学技术大学化学与材料科学学院 北京100101合肥230026合肥230026

【摘要】 贵金属Pd是甲醇分解反应常用的催化剂 ,本文综述了不同载体负载的Pd催化剂的催化性能以及反应条件对其催化活性、选择性和稳定性的影响 ,并介绍了其中一些催化剂的制备方法 ,对催化反应动力学和催化机理进行了简要的概括。

【Abstract】 Palladium supported on different metal oxides has been used as a catalyst for the decomposition of methanol.The recent advances concerning the catalyst preparation,catalytic performance,reaction mechanism and kinetics are reviewed in this article.The Pd supported on different rate earth oxides has been proved to be a comparatively satisfactory catalyst for methanol decomposition.The importance to continue to probe the Pd cluster size by some advanced tools such as XANES and to correlate it with the catalytic activity has been stressed.

【关键词】 裂解甲醇Pd催化剂
【Key words】 PalladiumCatalystMethanolDecomposition
  • 【分类号】O643.3
  • 【被引频次】5
  • 【下载频次】241
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