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新型后过渡金属烯烃聚合催化剂——镍系烯烃聚合催化剂
New Type Late Transition Metal Catalysts for Olefin Polymerization——Nickel-based Olefin Polymerization Catalysts
【摘要】 镍系烯烃聚合催化剂是近年来受到广泛关注的一类新型催化剂 ,是配位催化研究的热点之一。这类催化剂具有高催化活性、单活性中心和良好的分子剪裁性 ,可以在分子层次上实现烯烃聚合的分子设计与组装。本文介绍了镍系烯烃聚合催化剂的发现和研究概况 ,并评述了聚合特性及最新研究进展
【Abstract】 Nickel-based olefin polymerization catalysts are new-type catalysts, which have been attracted much attention in recent years. Nickel-based catalysts possess high catalytic activity for olefin polymerization, with single active center and wonderful molecular tailoring properties.In the present review, the discovery, development, the polymerization characteristics and the most significant studies on the nickel-based olefin polymerization catalysts are reported.
【关键词】 镍系催化剂;
后过渡金属催化剂;
烯烃聚合反应;
【Key words】 nickel-based catalysts; late transition metal catalysts; olefin polymerization;
【Key words】 nickel-based catalysts; late transition metal catalysts; olefin polymerization;
【基金】 国家自然科学基金 ( 2 99740 2 9,2 992 5 10 1);国家重点基础研究专项经费 ( G19990 64 80 0 )资助项目
- 【文献出处】 化学进展 ,Progress In Chemistry , 编辑部邮箱 ,2003年01期
- 【分类号】O643.3
- 【被引频次】31
- 【下载频次】797