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树脂吸附法处理磺胺脒生产废水的工艺

Treatment of Sulfanilamide Production Wastewater by Resin Adsorption Technique

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【作者】 许月卿彭应登赵仁兴

【Author】 Xu Yueqing 1,2, Peng Yingdeng 3, Zhao Renxing 4(1.Department of Resources,Environment and Geography, College of Environmental Sciences,Peking University,Beijing\ 100871,China ; 2. Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing 100101, China; 3. Beijing Municipal Research Academy of Environmental Protection, Beijing 100037, China; 4. College of Environmental Science and Technology, Hebei University of Science and Technology, Shijiazhuang 050018, China)

【机构】 北京大学环境学院资源环境地理系北京市环境保护科学研究院河北科技大学环境科学与工程学院 北京100871中国科学院地理科学与资源研究所北京100101北京100037石家庄050018

【摘要】 针对磺胺脒生产废水的特点 ,本研究确定了采用树脂吸附法回收磺胺、进一步回收硝酸钠的工艺流程 ,探讨了树脂对磺胺吸附 解吸的最佳工艺条件 .结果表明 :DRHⅢ型大孔吸附树脂对磺胺具有良好的吸附 解吸效果 ,能将有机物和无机物很好地分离 .经树脂吸附处理后 ,废水中COD去除率 86 % ,硝酸钠回收率 95 % ,磺胺回收率86 % ,其纯度达 99 8% .在废水有效处理的同时实现了废物资源化 ,具有良好的环境效益和较高的经济效益 .

【Abstract】 According to the character of sulfanilamide production wastewater, in this paper, the recovery process of sulfanilamide, sodium nitrate in wastewater resulting from manufacturing sulfanilamide was developed by using macro porous resin. The conditions of the resin adsorption and desorption capacity were investigated and the optimal parameters were determined. The results of experiment indicated that this technique was suitable for removal of sulfanilamide from wastewater. About 86% COD removal was obtained under the optimized adsorption conditions, about 86% sulfanilamide and 95% sodium nitrate were recovered from wastewater for possible recycling to the manufacturing process and the recovered sulfanilamides purity reached 99.8%. The adsorption capacity of resin remained constant during the repetition process of adsorption and desorption. This technique not only eliminates the environmental pollution but also obtain distinct economic benefit.

【基金】 中国科学院知识创新工程项目 (KZCX2 310 )
  • 【文献出处】 环境科学 ,Environmental Science , 编辑部邮箱 ,2003年06期
  • 【分类号】X703
  • 【被引频次】16
  • 【下载频次】318
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