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相转移催化合成新型含硫氧螯合树脂(英文)

SYNTHEIS OF A NOVEL CHELATING RESIN CONTAINING SULFUR AND OXYGEN UNDER PHASE TRANSFER CATALYZED CONDITIONS

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【作者】 曲荣君成国祥纪春暖王春华

【Author】 QU Rong jun 2) CHENG Guo xiang (School of Materias Science & Engineering, Tianjin University, Tianjin,370002) JI Chun nuan WANG Chun hua (Department of Chemistry, Yantai Normal College, Yantai,264025)

【机构】 天津大学材料科学与工程学院烟台师范学院化学系烟台师范学院化学系 天津370002烟台师范学院化学系天津370002烟台264025264025

【Abstract】 In this manuscript, a novel chelating resin containing sulfur and oxygen, poly[(2 hydroxyethyl) o vinylbenzene sulfide](PSSE), was synthesized by using chloromethylated polystyrene(PSC)and 2 mercapto ethanol(ME)as materials and tetrabutyl ammonium bromide(TBAB)as PT catalyst. The structure of PSSE was characterized by the methods of FTIR, elemental analysis, and X ray photoelectron spectroscopy(XPS). The effect factors such as reaction time, reaction temperature, and polarity of solvents on reaction were investigated.

【基金】 ThisworkwassupportedbyNatureScienceFoundationofShandongProvince (No.Q99B1 5 )andNationalNaturalScienceFoundation (No 2 990 60 0 8) .
  • 【文献出处】 环境化学 ,Environmental Chemistry , 编辑部邮箱 ,2003年03期
  • 【分类号】O643.3
  • 【被引频次】3
  • 【下载频次】80
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