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含氯废弃物燃烧过程中HCl排放特性

HCl EMISSION DURING CHLORIDE WASTES COMBUSTION PROCESS

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【作者】 李晓东杨忠灿严建华陆胜勇倪明江岑可法

【Author】 LI Xiaodong, YANG Zhongcan, YAN Jianhua, LU Shengyong, NI Mingjiang and CEN Kefa (Clean Energy and Environment Engineering Key Laboratory of Ministry Education, Zhejiang University,Hangzhou 310027, Zhejiang,China)

【机构】 浙江大学能源洁净利用与环境工程教育部重点实验室浙江大学能源洁净利用与环境工程教育部重点实验室 浙江杭州310027浙江杭州310027浙江杭州310027

【Abstract】 The emission characteristics of HCl during the chloride waste combustion process are studied in this paper PVC, PCP, NaCl are fired separately or mixed with each other, or co fired with coal in a pipe stove The results of the study indicate that chlorine in PVC and PCP would be emitted predominantly as HCl in a short time Chlorine in PVC could be released completely from 200 ℃ to 600 ℃.The conversion rate of chlorine to HCl from PCP is not as high as from PVC In addition, moisture is not the decisive factor that influences HCl emission Oxygen concentration promotes HCl formation very effectively In reactions related to coal, chlorine conversion for NaCl increases because of the effect of sulfur The formation rate of the chlorine molecule decreases when water vapor exists Even though oxygen is in excess, the formation rate is low, about 0 8%

【关键词】 HClPVCPCPNaCl垃圾焚烧
【Key words】 HClPVCPCPNaClwasteincineration
【基金】 国家重点基础研究发展规划项目 (No G19990 2 2 2 11)~~
  • 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,2003年10期
  • 【分类号】X705
  • 【被引频次】20
  • 【下载频次】231
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