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辉光放电等离子体增强制备甲烷催化燃烧的高分散Pd/Al2O3催化剂

PLASMA-ENHANCED PREPARATION OF HIGHLY DISPERSED Pd/Al2O3 CATALYST FOR CATALYTIC COMBUSTION OF METHANE

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【作者】 韩森于开录何琲刘昌俊

【Author】 HAN Sen,YU Kailu,HE Fei and LIU Changjun (State Key Laboratory of C1 Chemistry and Technology, School of Chemical Engineering,Tianjin University, Tianjin 300072,China)

【机构】 天津大学化工学院一碳化学与化工国家重点实验室天津大学化工学院一碳化学与化工国家重点实验室 天津300072天津300072天津300072

【Abstract】 A novel Pd/Al 2O 3 catalyst prepared by glow discharge plasma technology is reported.The results of H 2-chemisorption indicate that palladium dispersion of the plasma-prepared Pd/Al 2O 3 reaches 29.7%,which is about 5 times higher than Pd/Al 2O 3 prepared by conventional preparation.Meanwhile,the particle diameter of the plasma-prepared catalyst is 3.8 nm, but the particle diameter of the conventional catalyst is 20.4 nm.Such plasma-prepared Pd/Al 2O 3 catalyst shows a higher activity for catalytic combustion of methane than the conventional catalyst.Methane conversion reaches 90% at 400 ℃, but it is only near 30% for the conventional catalyst at the same temperature.

【基金】 教育部重点基金资助课题~~
  • 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,2003年05期
  • 【分类号】TQ426
  • 【被引频次】14
  • 【下载频次】218
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