【摘要】 概述了含氟新试剂全(多)氟酰基过氧化物的合成、热分解及其与富电子芳香族受物间的单电子转移反应的机理,并对其中生成的芳香族阳离子基的结构碎片化途径及其影响因素做了较深入的论述。还简要地介绍了它作为对芳环、芳杂环有效的全氟烷基化试剂及烯烃聚合的引发剂在合成含氟功能化合物领域中的重要作用。更多还原

【Abstract】 The synthesis of per(poly)fluorodiacyl peroxides,the kinetic studies and product analysis of their thermal decomposition,the mechanism investigation of their electron-transfer reactions with ele ctron-rich aromatics and nitrogen-containing substrates as well as their applications as effective aromatic ring-per(poly)fluoroalky-lating agents and initi ators of oligomerization are review ed in this paper.更多还原