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相转移催化在芳香氟化反应中的应用
Applications of Phase Transfer Catalysis in Aromatic Fluorination Reaction
【摘要】 介绍芳香氟化物制备方法,芳胺重氮化/热分解法、卤素交换法,氟化反应中4种常用的相转移催化剂冠醚、季铵盐、四苯基膦盐、聚乙二醇,及在氟化反应中的应用。对氟化反应相转移催化剂的发展方向进行了初步探讨。
【Abstract】 Arylamine diazotization, thermal decomposition, halogen exchange for aromatic fluoride preparation, four kinds of commonly used phase transfer catalysts crown ether, quaternary ammonium salt, tetraphenyl phosphonium salt, polyethylene glycol and their applications in fluorination reaction are introduced. Developing trends of phase transfer catalysts for fluorination reaction are also explored.
【关键词】 相转移催化;
相转移催化剂;
氟化反应;
【Key words】 phase transfer catalysis; phase transfer catalyst; fluorination reaction;
【Key words】 phase transfer catalysis; phase transfer catalyst; fluorination reaction;
- 【文献出处】 化工生产与技术 ,Chemical Production and Technology , 编辑部邮箱 ,2003年02期
- 【分类号】O643.3
- 【被引频次】13
- 【下载频次】401