【摘要】 以自制的蒎烷氢过氧化物为原料 ,经催化加氢还原制得高顺式选择性蒎烷醇。通过对催化剂种类、反应温度、反应压力和反应时间等主要因素的研究 ,确定了最佳合成工艺条件 :反应温度 35℃、反应压力 6MPa、反应时间 5h ,目的产物最大得率达 90 .0 6 %。更多还原

【Abstract】 Pinanol is essential intermediate in the process of the synthesis of linalool.In this paper,pinanol is obtained from pinane hydroperoxide.In the systhetic process,catalytic deoxidation reaction is emphatically concerned.Proper catalyst is selected,main factors influencing the reaction are experimented,and optimum condition is obtained.The maximum yield of pinanol 90.02 % is reached under the optimum catalytic deoxidizing condition—temperature 35℃,pressure 6 MPa,and time 5 h.更多还原