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TiO2光催化降解吡啶的研究

A Study of Photocatalytic Degradation of Pyridine in TiO2 System

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【作者】 钟俊波沈昱兰仁杰徐锁洪

【Author】 ZHONG Jun-bo,SHEN Yu,LAN Ren-jie,XU Suo-hong (Dalian Railway Institute,Dalian116028,China)

【机构】 大连铁道学院大连铁道学院 辽宁大连116028辽宁大连116028辽宁大连116028

【摘要】 以钛酸四丁酯水解法制备TiO2,采用溶胶-凝胶法在膨胀珍珠岩上负载TiO2,在UV-TiO2体系中对水中吡啶进行光催化降解,结果表明:TiO2加入量为1.25mg/mL,吡啶的光催化降解符合一级动力学方程,加入0.2%H2O2可明显加快吡啶的降解速度,吡啶中氮转化为氨氮,珍珠岩负载型TiO2与粉末TiO2具有相同的催化效能,且便于回收和重复使用。

【Abstract】 TiO 2 was prepared by a method of tetrabutyl titanate hydrolysis and was loaded onto ex panded pearlite by a pyrosol-gel method.The pyridine in water was photocatalytically degradated in a UV-TiO 2 system.The result of the test showed that the fed quantity of TiO 2 was1.25mg/mL,the photocatalyt ic degradation of the pyridine was in conformity with the first order kinetic equation,the feeding of0.2%H 2 O 2 obviously increased the degradation rate of the pyridine and the nitrogen in the pyridine converted into ammonia nitrogen;the pearlite-loaded TiO 2 had the same catalytic effect as that of powered TiO 2 and was easy to recover and reutilize.

【关键词】 二氧化钛光催化吡啶废水处理
【Key words】 TiO 2photocatalysispyridinewastewater treatment
  • 【文献出处】 工业用水与废水 ,Industrial Water & Wastewater , 编辑部邮箱 ,2003年05期
  • 【分类号】X703.5
  • 【被引频次】22
  • 【下载频次】205
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