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Electro-catalytic oxidation of phenol with Ti-base lead dioxide electrode

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【作者】 王东田魏杰于秀娟杨红

【Author】 WANG Dong tian, WEI Jie, YU Xiu juan, YANG Hong (Dept. of Applied Chemistry, Harbin Institute of Technology, Harbin 150001, China)

【机构】 Dept. of Applied ChemistryHarbin Institute of TechnologyHarbin Institute of Technology Harbin 150001ChinaHarbin 150001China

【Abstract】 The Ti base PbO 2 electrode prepared by electrodeposition of PbO 2 on the surface of titanium was used for electro catalytic oxidation of phenol in waste water. The experimental results show that the electrodeposition of PbO 2 at a higher current density for a short time, then followed by a lower current density can get a compact and combinative PbO 2 layer. The properties of a Ti/PbO 2 electrode with an interlayer of oxide are the best. When this kind of electrode is used to treat phenol containing waste water, the phenol removal rate is higher and the slot voltage is lower. In addition, by using the phenol removal rate as an index, the influences of electrolysis current density, mass transfer condition and pH were studied and the optimal condition was confirmed.

【基金】 ScientificResearchFoundationofHarbinInstituteofTechnology(GrantNo .HIT .2 0 0 0 0 110 0 677)
  • 【文献出处】 Journal of Harbin Institute of Technology ,哈尔滨工业大学学报(英文版) , 编辑部邮箱 ,2003年01期
  • 【分类号】O625
  • 【被引频次】1
  • 【下载频次】44
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