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掺铒铝硅酸盐玻璃光谱和上转换荧光性质研究
Spectroscopic and Upconversion Fluorescence Properties of Er3+ Doped Aluminosilicate Glass
【摘要】 利用Judd Ofelt(J O)理论和吸收光谱计算了Er3 +、Yb3+掺杂的铝硅酸盐玻璃的J O参量、振子强度、跃迁几率、荧光寿命 ,量子效率以及上转换系数等参量 ,比较了铒离子4 I13/ 2 →4 I15/ 2 跃迁的光谱参量的计算与测量值 ,并讨论了玻璃中OH-浓度与荧光寿命、绿色上转换发光强度与抽运光功率的关系。
【Abstract】 The Judd-Ofelt parameters, oscillator strengths, radiative transition probability, radiative lifetime,quantum efficiency and upconversion coefficient of the Er 3+, Yb 3+ co-doped aluminosilicate glasses were calculated by the Judd-Ofelt theory, fluorescent lifetime and absorption spectra. The effect of Yb 3+ and Er 3+ ion concentrations, OH -groups on the spectroscopic and upconversion fluorescence properties was studied in this Er 3+, Yb 3+ co-doped aluminosilicate glass. It is found that at 1.56×10 20 cm -3 Yb 3+ and Er 3+ ion concentrations, the glass has the best spectroscopic properties.
【Key words】 optical material; aluminosilicate glass; Er 3+, Yb 3+ co-doping; spectra; Judd-Ofelt parameters; upconversion;
- 【文献出处】 光学学报 ,Acta Optica Sinica , 编辑部邮箱 ,2003年04期
- 【分类号】TQ171.718.2
- 【被引频次】20
- 【下载频次】264