【摘要】 在甲醇溶剂中合成了标题配合物[Co(C9H6NO3)3]·CH3OH,测定了其晶体结构,晶体属单斜晶系,P2(1)/n空间群.晶胞参数a=1.0872(1),b=1.3122(2),c=1.6681(2)nm;β=97.661(1)°,V=2.3585(5)nm3,Z=4,F(000)=1080,Dc=1.474g/cm3,μ=0.769mm-1,S=1.023.配合物中Co( )离子是六配位变形八面体结构.更多还原

【Abstract】 Tris (8hydroxyquinolinato) cobalt(Ⅲ) methanol solvate is synthesized through the reaction of 8hydroxyquinoline with Co(Ac)2.Its crystal structure is determined by single crystal Xray diffraction.The crystal structure of the title complex belongs to monoclinic system with space group P2(1)/n and unite cell parameters:a=1.0872(1),b=1.3122(2),c=1.6681(2)nm;β=97.661(1)°,V=2.3585(5)nm3,Z=4,F(000)=1080.Dc=1.474g/cm3,μ=0.769mm-1,S=1.023.In the crystal structure of the title compound,Co(Ⅲ) ion is sixcoordinated to form a distorted octahedron.更多还原