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立方氮化硼表面硬化层的制备及性能

Preparation and Properties of Hardened Surface Layers Containing Cubic Boron Nitride

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【作者】 王钧石柳襄怀王曦陈元儒

【Author】 WANG Junshi1, LIU Xianghuai2, WANG Xi2, CHEN Yuanru1(1. Southwest Jiaotong University, Chengdu 610031, China; 2. Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China)

【机构】 西南交通大学材料科学与工程学院中国科学院上海微系统与信息技术研究所离子束重点实验室西南交通大学材料科学与工程学院 四川成都610031上海200050四川成都610031

【摘要】 用渗硼和新型的等离子体浸没式氮离子注入技术(PⅢ)对Cr12MoV钢进行复合处理,制备出了含有立方氮化硼的表面硬化层。经X光电子能谱和X射线衍射分析发现硬化层中的组织主要是立方氮化硼(c BN)、六方氮化硼(h BN)、FeB和Fe2B。在与单独渗硼处理的Cr12MoV钢试样进行对比时,对立方氮化硼表面硬化层进行了维氏显微硬度和滑动摩擦试验。结果表明:硬化层具有高达48GPa的高硬度和优良的摩擦性能。

【Abstract】 The hardened surface layers containing cubic boron nitride (cBN) phase on Cr12MoV steel were prepared by a double treatment combining boronizing and a new plasma immersion nitrogen ion implantation (PⅢ) technique. It was found by xray photoelectron spectroscopy (XPS) and xray diffraction (XRD) analysis that the main structures were cubic boron nitride (cBN), hexagonal boron nitride(hBN), FeB and Fe2B in the hardened surface layers. The hardness and tribological properties of the hardened surface layers were determined by Vickers micro hardness experiment and sliding friction experiment in comparison with the specimens of Cr12MoV steel treated alone by boronizing. The results indicated that the hardened surface layers had very high hardness up to 48GPa and very fine tribological properties.

【基金】 中国科学院上海微系统与信息技术研究所离子束重点实验室基金资助项目(100027)
  • 【文献出处】 机械工程材料 ,Materials For Mechanical Engineering , 编辑部邮箱 ,2003年02期
  • 【分类号】TG174.4
  • 【被引频次】3
  • 【下载频次】179
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