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腐植酸溶液声化学降解过程中的紫外光谱研究
Ultraviolet Spectra Study on Humic Acid Degradation Process by Sonochemistry
【摘要】 研究了腐植酸溶液超声声化学降解过程中近紫外光谱在190-320 nm间的变化,证明超声波对腐植酸有明显的降解作用,并测定了降解过程中不同pH值条件下TOC的变化,对降解过程的自由基氧化历程进行了分析。
【Abstract】 The changes of ultraviolet spectra in the range of 190-320 nm of the humic acid sonochemical degradation process were studied. The experimental results show that the ultrasound has a high degradability to humic acid. The TOC removel rates in different pH ranges were 896-15%. In the low pH condition, the TOC removel rate is low, however, in the high pH condition, the TOC removel rate is higher. Futhermore, the free radical oxidation process was analyzed.
【关键词】 超声波;
声化学;
腐植酸;
紫外光谱;
TOC削减;
【Key words】 Ultrasound; Sonochemistry; Hurhic acid; Ultraviolet spectra; TOC removel;
【Key words】 Ultrasound; Sonochemistry; Hurhic acid; Ultraviolet spectra; TOC removel;
【基金】 环境模拟与污染控制联合实验室(940203)资助
- 【文献出处】 光谱学与光谱分析 ,Spectroscopy and Spectral Analysis , 编辑部邮箱 ,2003年05期
- 【分类号】O657.3
- 【被引频次】8
- 【下载频次】206