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Rb(7D)+Na(3S)碰撞激发转移过程

Excitation Transfer Process Rb(7D)+Na(3S) Collisions

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【作者】 沈异凡沈晓燕

【Author】 SHEN Yi-fan 1, SHEN Xiao-yan 2 1.Department of Physics, Xinjiang University, Urumqi 830046, China 2.Department of Chemistry, East China University of Science and Technology, Shanghai 200237, China

【机构】 新疆大学物理系华东理工大学化学系 新疆乌鲁木齐830046上海200237

【摘要】 研究了Rb Na异核系统的能量碰撞合并逆过程 (REP)。两步激发Rb原子到 7D3 / 2 态。应用双调制技术探测Na(3Pj)原子发射的荧光 ,基态Na原子密度用光学吸收方法测量。得到了REP率系数 ,讨论了其他过程对率系数的影响。

【Abstract】 The observation of a heteronuclear reverse energy pooling process is reported. The cross sections for the collision processes Rb(7 D )+Na(3 S )→Rb(5 P )+Na(3 P ) have been measured. In the experiment the rubidium atoms were excited in two steps to the 7 D _ 3/2 state. A double-modulation technique has been used to select the fluorescence contributions at the Na(3 P_j ) exit channels due only to the above reactions. The ground state sodium atom density was measured by the absorption of line from a Na hollow-cathode lamp. The measured density and fluorescence intensities have been used to obtain reverse energy pooling rate coefficients. The contribution to the rate coefficients from other processes is discussed.

【基金】 国家自然科学基金 (1 98640 0 1 )资助项目
  • 【文献出处】 光谱学与光谱分析 ,Spectroscopy and Spectral Analysis , 编辑部邮箱 ,2003年04期
  • 【分类号】O562.5
  • 【下载频次】40
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