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纤维上染料的老化紫外光谱分析

UV Spectral Analysis of Dye Degradation on Fibers

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【作者】 张永金张波兰宋心远

【Author】 ZHANG Yong-jin ZHANG Bo-lan SONG Xing-yuan(Wuhan Institute of Science and Technology, Wuhan 430073; Donghua University, Shanghai 200051)

【机构】 武汉科技学院环化系东华大学 武汉 430073武汉 430073上海 200051

【摘要】 本文通过模拟纤维使用过程中所经历的光照、氧化和还原等环境作用因素,用紫外光谱的方法研究了几种染料的化学结构的变化,其中光化学变化、氧化还原烟气(NO2、H2S等)作用是影响染料老化的几个重要因素之一,光化学作用是使染料发生化学变化(如偶氮键断裂)的主要因素。

【Abstract】 Several dyes were studied by exposing them to conditions that imitate environmental factors that affect fibers during application, such as light exposure, oxidation and reduction. Chemical structural changes in the dyes were then examined by UV. It was found that photochemical changes and the effects of oxidative and reductive gasses (NO2, H2S, etc.) were the main factors affecting dye degradation on fibers, and that photochemical effects were the primary factor leading to chemical changes (such as breaking azo bonds) in the dyes.

【关键词】 染料老化紫外
【Key words】 dye degradationUV spectra analysis
  • 【文献出处】 染料与染色 ,Dyestuffs and coloration , 编辑部邮箱 ,2003年05期
  • 【分类号】TS193
  • 【被引频次】14
  • 【下载频次】287
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