节点文献
可逆加成—断裂链转移活性自由基聚合
Living Radical Polymerization with Reversible Addition-fragmentation Chain Transfer
【摘要】 介绍了可逆加成 -断裂链转移 (Reversibleaddition fragmentationchaintransfer,RAFT)活性自由基聚合的反应机理、聚合动力学和特点 ,对RAFT试剂的选择和制备作了简要介绍 ,并综述了RAFT聚合的发展动态及应用状况
【Abstract】 In this paper, the mechanism, kinetics and characteristics of the living radical polymerization with reversible addition\|fragmentation chain transfer (RAFT) are reviewed in detail. The principles of selecting a proper RAFT agent for a given polymerization, and the synthesis process of the agent are presented briefly. Additionally, the development and application of the RAFT polymerization were summarized.
【关键词】 活性自由基聚合;
双硫酯;
加成-断裂链转移;
休眠种;
【Key words】 Living radical polymerization; Dithioester; Addition\|fragmentation chain transfer; Dormant species;
【Key words】 Living radical polymerization; Dithioester; Addition\|fragmentation chain transfer; Dormant species;
【基金】 国家留学基金资助
- 【文献出处】 高分子通报 ,Polymer Bulletin , 编辑部邮箱 ,2003年03期
- 【分类号】O631.5
- 【被引频次】50
- 【下载频次】2123