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导电聚苯胺的特性,应用及进展

PROPERTIES AND APPLICATIVE VIEW OF POLYANILINE

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【作者】 于黄中陈明光贝承训黄河

【Author】 YU Huang-zhong 1, CHEN Ming-guang 1, BEI Cheng-xun 1, HUANG He 2 (1.Depart. of Applied Physics, South China University of Tech., Guangzhou 510640, China; 2.Dept. of Physics, Southchina Normal University, Guangzhou 510631, China)

【机构】 华南理工大学应用物理系华南师范大学物理系 广东广州510640广东广州510640广东广州510631

【摘要】 导电聚苯胺是极有前途的导电聚合物 ,它能够广泛地应用于二次电池、金属的防腐、电致发光器件的电极修饰等方面。文中综述了导电聚苯胺的结构、特性、应用前景、进展及其面临的问题

【Abstract】 Polyanilne is one of the most perspective conductive polymers among the many types of conducting polymers due to its straightforward polymerization, environmental stability, and relative high conductivity. It possesses widely applications such as battery electrodes, and electrochromic and electronic devices. Structure characteristics, physical and chemical properties, technical application, progress and challenge for the conducting polymers were described. It can be synthesized by chemical or electrochemical oxidation of aniline. Polymerization of PANI is accomplished by head-to-tail coupling. When PANI is in a half-oxidized state, which becomes conductive upon protonic acid doping. The major disadvantage of PANI is its insolubility in common organic solvents and its infusibilty. But this shortage is gotten over slowly, the PANI will come into applied phase.

【关键词】 聚苯胺导电高分子掺杂应用
【Key words】 polyanilineconductive polymerdopingapplication
【基金】 国家自然科学基金 ( 60 0 760 13 );广东省自然科学基金 ( 990 44 6);广东省重点科技攻关项目 ( 3 2 0 10 0 )
  • 【文献出处】 高分子材料科学与工程 ,Polymeric Materials Science & Engineering , 编辑部邮箱 ,2003年04期
  • 【分类号】O633.2
  • 【被引频次】169
  • 【下载频次】2194
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