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聚羧酸型梳状共聚物超分散剂的构性关系研究

THE RELATIONSHIP BETWEEN STRUCTURES AND PROPERTIES OF COMB-SHAPED COPOLYMERS OF POLYCARBOXYLIC ACID TYPE USED AS SUPERPLASTICIZER

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【作者】 公瑞煜肖传健徐诗强石朝周王洛礼刘景民

【Author】 GONG Rui-yu, XIAO Chuan-jian, XU Shi-qiang, SHI Chao-zhou (Pharmaceutic College, Tongji Medical College, Huazhong University of Science and Technology, Wuhan 430030, China) WANG Luo-li, LIU Jing-min (Hubei Research Institute of Chemistry, Wuhan 430074, China)

【机构】 华中科技大学同济医学院药学院湖北省化学研究所湖北省化学研究所 湖北武汉430030湖北武汉430030湖北武汉430074湖北武汉430074

【摘要】 以聚氧乙烯甲基烯丙基二醚 (APEO- n)、顺丁烯二酸酐 (MAn)、苯乙烯 (St)等为共聚单体 ,合成了一系列聚羧酸型梳状共聚物 ,研究了共聚物的结构、组成等对分散性能的影响。结果表明 ,接枝链的长度和密度影响超分散剂的性能 ,当接枝链长度为 2 0~ 60、St% (mol% )为 5 %~ 2 0 %时 ,分散性能良好

【Abstract】 A series of comb-shaped copolymers of polycarboxylic acid type with polyoxyethylene allyl methyl diether(APEO-n), maleic anhydride(MAn), and/or styrene(St) were synthesized. The effects of structure and composition of copolymers on dispersing capability were studied. The results show that the properties of superplastisizer are effected by length and density of graft chain. The superplasticizer has excellent dispersing capability as the length of graft chain is 20~60, the content of St is 5 mol%~20 mol%.

  • 【文献出处】 高分子材料科学与工程 ,Polymeric Materials Science & Engineering , 编辑部邮箱 ,2003年01期
  • 【分类号】TQ316.34
  • 【被引频次】19
  • 【下载频次】384
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