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1-烯丙基,3-甲基咪唑室温离子液体的合成及其对纤维素溶解性能的初步研究

SYNTHESIS OF 1-ALLYL,3-METHYLIMIDAZOLIUM-BASED ROOM- TEMPERATURE IONIC LIQUID AND PRELIMINARY STUDY OF ITS DISSOLVING CELLULOSE

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【作者】 任强武进张军何嘉松过梅丽

【Author】 REN Qiang 1,2, WU Jin2, ZHANG Jun2, HE Jiasong2, GUO Meili1 ( 1School of Material Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing100083) ( 2State Key Laboratory of Engineering Plastics, Center for Molecular Scien ce, Institute of Chemistry, Chinese Academy of Sciences, Beijing100080)

【机构】 北京航空航天大学材料科学与工程学院中国科学院化学研究所分子科学中心工程塑料国家重点实验室北京航空航天大学材料科学与工程学院 北京100083中国科学院化学研究所分子科学中心工程塑料国家重点实验室北京100080北京100080北京100083

【Abstract】 A novel room-temperature ionic liquid (RTIL),1-allyl,3-methylimidazolium chloride ([AMIM]Cl),was synthesized,ch aracterized and used for dissolving cellulose.The solubility of cellulose in [ AMIM]Cl was better than in 1-butyl,3-methylimidazolium ([BMIM]Cl).The pris tine cellulose and two cellulose samples regenerated from [AMIM]Cl and [BMIM ]Cl solutions were compared by FTIR,WAXD and TGA measurements.Results show t hat these two RTILs are non-derivatizing solvents for cellulose.After regenera tion from RTIL solutions,the crystalline form of cellulose films is completely transformed from cellulose Ⅰ to cellulose Ⅱ.Compared to pristine cellulose,t he regenerated cellulose exhibits a lower onset temperature of thermal decomposi tion,with a higher char yield.

【关键词】 室温离子液体溶解纤维素
【Key words】 Room-temperature ionic liquidDissolutionCellulos e
【基金】 国家自然科学基金 (基金号 5 0 10 30 11)资助项目
  • 【文献出处】 高分子学报 ,Acta Polymerica Sinica , 编辑部邮箱 ,2003年03期
  • 【分类号】O645
  • 【被引频次】473
  • 【下载频次】4179
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