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1-烯丙基,3-甲基咪唑室温离子液体的合成及其对纤维素溶解性能的初步研究
SYNTHESIS OF 1-ALLYL,3-METHYLIMIDAZOLIUM-BASED ROOM- TEMPERATURE IONIC LIQUID AND PRELIMINARY STUDY OF ITS DISSOLVING CELLULOSE
【Abstract】 A novel room-temperature ionic liquid (RTIL),1-allyl,3-methylimidazolium chloride ([AMIM]Cl),was synthesized,ch aracterized and used for dissolving cellulose.The solubility of cellulose in [ AMIM]Cl was better than in 1-butyl,3-methylimidazolium ([BMIM]Cl).The pris tine cellulose and two cellulose samples regenerated from [AMIM]Cl and [BMIM ]Cl solutions were compared by FTIR,WAXD and TGA measurements.Results show t hat these two RTILs are non-derivatizing solvents for cellulose.After regenera tion from RTIL solutions,the crystalline form of cellulose films is completely transformed from cellulose Ⅰ to cellulose Ⅱ.Compared to pristine cellulose,t he regenerated cellulose exhibits a lower onset temperature of thermal decomposi tion,with a higher char yield.
- 【文献出处】 高分子学报 ,Acta Polymerica Sinica , 编辑部邮箱 ,2003年03期
- 【分类号】O645
- 【被引频次】473
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