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在H型分子筛上萘与正己醇的烷基化反应
Alkylation of Naphthalene with n-Hexanol over H-type Zeolites
【摘要】 制备了 H型分子筛 HY,Hβ和 HM,通过 XRD,NH3 -TPD和 Py-IR对其进行了表征 ,考察了其对萘与正己醇的烷基化反应的催化性质 .结果表明 ,HY可作为己基化反应的催化剂 ,较高的反应温度和较长的反应时间对 β-己基萘的生成有利 .
【Abstract】 HY, Hβ and HM zeolites were synthesized and characterized by XRD, NH 3-TPD and Py-IR. Selectively catalytic alkylation of naphthalene with n-hexanol to hexyl-naphthalene over the zeolites has been examined. The experimental results show that HY zeolite can be used as a catalyst for the title reaction and shows a higher naphthalene conversion. Higher reaction temperature and longer reaction time are beneficial for the production of β-hexyl-naphthalene over HY zeolite.
【关键词】 分子筛;
萘;
正己醇;
己基-萘;
烷基化;
【Key words】 Zeolite; Naphthalene; n-Hexanol; n-Hexyl naphthalene; Alkylation;
【Key words】 Zeolite; Naphthalene; n-Hexanol; n-Hexyl naphthalene; Alkylation;
【基金】 国家留学基金委 ( CSC)资助;教育部留学人员科研启动基金资助课题
- 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2003年10期
- 【分类号】O643.3
- 【被引频次】1
- 【下载频次】151