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电化学双石英晶体阻抗分析新方法

A Novel Method for Electrochemical Dual Quartz Crystal Impedance Analysis

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【作者】 谢青季张友玉杨晓辉李萌何红梅姚守拙

【Author】 XIE Qing-Ji *, ZHANG You-Yu, YANG Xiao-Hui, LI Meng, HE Hong-Mei, YAO Shou-Zhuo (Chemical Research Institute, Hunan Normal University, Changsha 410081, China)

【机构】 湖南师范大学化学研究所湖南师范大学化学研究所 长沙410081长沙410081长沙410081

【Abstract】 A novel method for simultaneous impedance analyses of two resonating piezoelectric quartz crystals is proposed via the admittance measurements of two crystals in parallel and then nonlinear admittance fitting to an equivalent circuit of two Butterworth-Van Dyke circuits in parallel. Series of sucrose aqueous solutions and copper electro-deposition/stripping in a NH 3-(NH 4) 2SO 4 buffer were used to test this method, giving that the impedance parameters of each of the parallel crystals reflecting the solution density-viscosity effect or the mass effect were very close to those measured with each single crystal alone. Also, simultaneous impedance measurements at the working and counter electrodes were carried out and discussed.

【基金】 国家自然科学基金 (批准号 :2 0 2 75 0 10 );全国高等学校优秀青年教师教学科研奖励计划 (教人司 [2 0 0 0 ] 2 6号 )资助
  • 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2003年10期
  • 【分类号】O657.1
  • 【被引频次】1
  • 【下载频次】155
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